In this method, small amount of sodium hexafluorophosphate (NaPF(6), as an ion-pairing agent) was added to the sample solution containing very small amount of 1-hexyl-3-methylimidazolium tetrafluoroborate ([Hmim][BF(4)], as hydrophilic IL). The method is based on the cold-vapor technique (CVAAS). The influence of eluting agents, the minimum volume and maximum flow rate of the eluent, and interfering ions on cobalt(II) was studied. Amberlite XAD‐4 functionalized with 3,4‐dihydroxybenzoic acid packed in a minicolumn was used as metal sorbent. The developed procedure is 10-fold more sensitive in comparison to the analogous procedure based on measurements in solution, being suitable for the determination of iron in water samples with good accuracy and precision. maximum extraction ( max), molar absorptivity (E) linear concentration range obeying Beer's law, effect of diverse ions, limit of detection (LOD), limit of quantification (LOQ), and preconcentration factor has been determined. A method for the determination of trace mercury in water samples by hydride generation atomic absorption spectrophotometry after cloud point extraction was proposed in the present work. The sorption of Pd(II) ions was quantitative in the pH range of 1.5-5.0, whereas quantitative desorption occurred with 5.0 mL of a mixture containing 1.0 M thiourea and 1.0 M HCl. A variety of parameters affecting the signal, such as pH, DTZ concentration, sample and extraction solvent volume, extraction time and temperature and salt effects were optimized. Determination of total iron in water and foods by dispersive liquid-liquid microextraction coupled with microvolume UV-vis spectrophotometry. This effort has led to the development of various liquid phase microextractions namely single drop microextraction (SDME), hollow fiber liquid phase microextraction (HF-LPME), dispersive liquid-liquid microextraction (DLLME) and solidified floating organic drop microextraction (SFODME). Furthermore, this technique is much safer in comparison with the organic solvent extraction. Determination of trace inorganic mercury species in water samples by cloud point extraction and UV-vis spectrophotometry. CORRESPONDING AUTHOR. Samples of natural and waste water must be pre-treated using the appropriate standard digestion procedures. The recoveries of PAHs from surface water at spiking level of 5.0 microg/L were 82.0-111.0%. TiO2 NPs, pH of sample solution, ultrasonication and centrifugation time, TiO2 slurry solution preparation before injection to CV AAS were investigated. NLM The limits of detection were estimated as 2.3, 5.0, 7.8, and 0.1 µg L for copper, iron, nickel, and zinc, respectively, using a preconcentration time of 60 s and a sample flow rate of 5.5 mL min. Liquid–liquid extraction (LLE) is widely used as a pre-treatment technique for separation and preconcentration of both organic and inorganic analytes from aqueous samples. nitrogen cycle. Moreover, the quantification of Hg(2+) could be obtained by fluorescence detection of test solution. The developed CE method allows determination of psychotropic drugs at ng/ml level in human urine. COVID-19 is an emerging, rapidly evolving situation. In the present paper, a simultaneous pre-concentration procedure for the sequential determination of cadmium and lead in table salt samples using flame atomic absorption spectrometry is proposed. J Hazard Mater. A 135-fold sensitivity enhancement was achieved at a sampling frequency of 72 h-1 and with the consumption of 2.7 ml of sample solution. Morin has been reported as a spectrophotometric reagent for aluminum,8 but has not been used previously for the spectrophotometric determination of iron. This study reports the synthesis of water soluble iron(II) phthalocyanine and a facile method for spectrophotometric determination of Hg(II) in environmental water samples by ionic liquid based dispersive liquid–liquid microextraction (IL-DLLME). The four most common and reliable techniques for mercury determination are spectrophotometry after chelation with dithizone, atomic absorption and emission spectroscopy, neutron activation analysis, and gas chromatography. the sorbent, volume of the solutions and flow variables were studied as well as effect of potential interfering ions. The capacity of biosorbent for mercury(II) and methyl mercury was 6.5 and 5.4 mgg(-1), respectively. pH, concentration of V(V), concentration of reagent, and effect of solvents are optimized. (18) Hongmei, J., Yongchao, Q., & Bin, Martinis EM, Bertón P, Olsina RA, Altamirano JC, Wuilloud RG. 1.2. The method was applied for the evaluation of the concentration of cadmium and lead in table salt samples consumed in Salvador City, Bahia, Brazil. A cloud-point extraction method for preconcentration of ultra-trace quantities of mercury ions as a prior step to its determination by spectrophotometry. 1: University of Sistan and Baluchestan, IRAN. spiked solutions at 3 and 5 mg L−1 for the determination of mercury in tap water, drinking water, dental unit wastewater, and artificially prepared model water samples. In this method, small amount of sodium hexafluorophosphate (NaPF6, as an ion�pairing agent) A method has been developed for mercury(II) and methyl mercury speciation on Staphylococcus aureus loaded Dowex Optipore V-493 micro-column in the presented work, by using cold vapour atomic absorption spectrometry. http://dx.doi.org/10.1016/j.sab.2008.10.042, Amjadi, M., Manzoori, J.L., & Abulhassani, J. Most COD test kits use mercury … Catalytic Photometric Determination of Trace Hg in Environmental Water and Sewage Sludge Samples Baoqing Xiao Civil & Environment Engineering School, University of Science and Technology, Beijing, 100083, China Email:xiaobq@ces.ustb.edu.cn Abstract: Mercury is recognized as one of the most toxic elements, so the environmental water and sewage The cloudy state resulted from the dispersion of the fine particles of the sorbent in the bulk aqueous sample. Low limits of detection and quantification in the ranges of 1.6–12, and 5.5–42 ng kg ⁻¹ , relative standard deviations ≥6.1% (at a concentration of 50 ng kg ⁻¹ , each analyte) and extraction recoveries and enrichment factors in the ranges of 69–94% and 345–470, were obtained, respectively, under optimal conditions. A 500 ml PTFE-bottle attached to a sampling gear is used as sampling vessel for the cold vapour atomic absorption Spectrophotometry, using nitrogen aeration, SnCl2 reduction, and preenrichment/ purification by amalgamation on finely dispersed gold. To avoid systematic errors in the sampling and determination of mercury in seawater an integrated sampling-analyzing system has been developed. In this method, ChCl: phenol and ChCl: butyric acid deep eutectic solvents were used in the first and second steps mentioned above, respectively. The relative standard deviations of the procedure were below 7%. The influences of the some alkaline and earth alkaline ions and some transition metals on the recoveries were also investigated. USA.gov. The precision of the preconcentration procedure (evaluated as standard deviation of solutions containing 1.0–30.0 μg l−1 of cadmium) varied in the range from 5 to 1%. osti.gov journal article: determination of traces of mercury by spectrophotometry, atomic absorption, radioisotope dilution, and other methods. Optimal analytical conditions including pH, amounts of biosorbent, sample volumes, etc., were investigated. Several variables affecting microextraction efficiency and the ETAAS signal-such as pyrolysis and atomization temperature, pH, APDC concentration, extraction time, drop volume, and stirring rate-were investigated and optimized. Organic mercury is decomposed into to inorganic mercury by using a UV lamp. Furthermore, this technique is accurate determination of this metal ion at trace and ultra-trace levels. Thus an enrichment factor of ∼407 and the limit of fluorescence detection of 0.03μgL(-1) could be achieved. Results demonstrated that sample solutions containing cadmium(II) in the range of concentration from 0.91 to 30.00 μg l−1, pH between 6.50 and 9.25 could be determinated by this procedure, in a preconcentration time of 1 min. New terms are carefully defined as they are introduced, and each term is italicized for emphasis and for ease of relocation by the student who may forget its meaning. The metal ion is eluted as iron(II) with a small volume of a diluted acid solution without removing the immobilized reagent, which can be used for at least 100 determinations. NIH After the extraction of the Hg(II) complex (Hg(II):q-Fe(II)-Pc) into thin droplets of ionic liquid, the sample was centrifuged for 4 min at 2000 rpm. [1] It is a vital component for all known forms of life and is the aquatic habitat for thousands of species of microalgae, fish and shellfish. 21 and 33pg/mL for Co and Ni were 7.5 % and 8.2 %, respectively compared with of!, M. 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